한국해양대학교

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온도의존 실시간 라만분석을 통한 메탄올 하이드로퀴논의 구조적 변화 및 객체 거동에 관한 연구

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dc.contributor.author 남병욱 -
dc.date.accessioned 2017-02-22T06:44:32Z -
dc.date.available 2017-02-22T06:44:32Z -
dc.date.issued 2012 -
dc.date.submitted 56987-11-06 -
dc.identifier.uri http://kmou.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002175511 ko_KR
dc.identifier.uri http://repository.kmou.ac.kr/handle/2014.oak/9749 -
dc.description.abstract Hydroquinone (HQ) clathrate is one of the inclusion compounds formed from two or more molecular species and associated with the enclosure of guest molecules within hydrogen-bonded framework formed by the HQ host molecules. the structure of methanol-loaded HQ clathrate was checked by spectroscopy such as X-ray diffraction and Nuclear Magnetic Resonance. Especially the structural transition from methanol-loaded HQ clathrate to crystalline α-form hydroquinone was observed by in-situ Raman spectroscopy as a function of temperatures. The vibrational Raman bands at 1160 and 1600 cm-1 were used as an indication to determine the structural transition of the HQ clathrate. Temperature-dependent Raman measurements showed that the methanol-loaded HQ clathrate is stable at temperatures below 380 K and gradually transforms to the a-form of crystalline HQ between 380 ~ 410 K. At the transition region, we observed a dramatic decrease of the O-H stretching Raman band of methanol at 3627 cm-1, indicating the rapid release of methanol molecules from the HQ clathrate framework. -
dc.description.tableofcontents Abstract 제 1 장 서 론 1.1 연구배경 1.1.1 가스하이드레이트 (gas hydrate) 1.1.2 하이드로퀴논 (hydroquinone) 1.1.3 메탄올 (Methanol) 1.2 연구범위 제 2 장 실험장비 및 방법 2.1 메탄올 하이드로퀴논 제작 2.2 High resolution powder X-ray diffraction 2.2.1 실험원리 2.2.2 실험장비 및 방법 2.3 Nuclear Magnetic Resonance (NMR) Spectroscopy 2.3.1 실험원리 2.3.2 실험장비 및 방법 2.4 Raman spectroscopy 2.4.1 실험원리 2.4.2 실험장비 및 방법 제 3 장 실험결과 및 토의 3.1 하이드로퀴논 내 메탄올 포접 유무 확인 3.1.1 X선 회절분석 결과 3.1.2 핵자기 공명 분광 측정 결과 3.2 메탄올 하이드로퀴논의 열역학적 안정영역 파악 3.2.1 Raman 분광 측정 결과 3.2.2 In situ Raman 분광 측정 결과 제 4 장 결 론 참고문헌 -
dc.language kor -
dc.publisher 한국해양대학교 -
dc.title 온도의존 실시간 라만분석을 통한 메탄올 하이드로퀴논의 구조적 변화 및 객체 거동에 관한 연구 -
dc.title.alternative Structual Transformation and Guest Dynamics of Methanol-loaded Hydroquinone Clathrates Observed by Temperature-dependent In-situ Raman Spectroscopy -
dc.type Thesis -
dc.date.awarded 2012-02 -
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